Cross-metathesis of Brønsted acid-masked alkenyl amines with acrylates for the synthesis of polyamide monomers

Authors Szabolcs Solyom, Nicolas Daniel Spiccia, Clint Peter Woodward, William Roy Jackson, Andrea Jane Robinson
Published Journal of Organic Chemistry
Graphical abstract Nylon 2
Abstract Ruthenium-alkylidene catalyzed cross metathesis of a range of homologous alkenylamine salts provides expedient and high yielding routes to commercially valuable polyamide monomers using a single catalyst, telescopic workup and mild experimental conditions.
Citation Szabolcs Solyom, Nicolas Daniel Spiccia, Clint Peter Woodward, William Roy Jackson, Andrea Jane Robinson, J. Org. Chem., 2016, 81(5), 1798-1805
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Doi https://doi.org/10.1021/acs.joc.5b02484
Subjects Salts, Monomers, Catalysts, Organic compounds, Alkyls
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